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Steric hindrance in the addition of dichlorocarbene to olefins

✍ Scribed by Robert A. Moss; Andrew Mamantov

Publisher: Elsevier Science
Year: 1968
Tongue: French
Weight: 177 KB
Volume: 9
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89509-x

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✦ Synopsis

A recent reactivity comparison of dichlorocarbene and chlorofluorocarbene suggested that steric hindrance played an important role in determining the rate of the carbene-olefin addition reaction (1). Indeed, although warnings were is-

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