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1,4-Addition of dichlorocarbene to 1,2-bismethylenecycloheptane

โœ Scribed by L.A.M. Turkenburg; W.H. de Worlf; F. Bickelhaupt


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
144 KB
Volume
23
Category
Article
ISSN
0040-4039

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I - (2,4,-l -phosphaallene reacted with dichlorocarbene to give 2-dichloromethylene-l-(2,4,6-tri-t-butylphenyl)-l -phosphirane. The structure was confirmed by X-ray crystal structure analysis. A similar isomerization product was obtained in the reaction of dichlorocarbene with 3-phenyl-l-(2,4,6-trit