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Reaction of dichlorocarbene with 1-(2,4,6-tri-t-butylphenyl)-1-phosphaallenes

✍ Scribed by Masaaki Yoshifuji; Manabu Shibata; Kozo Toyota; Ikuko Miyahara; Ken Hirotsu

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
536 KB
Volume
5
Category
Article
ISSN
1042-7163

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✦ Synopsis

I - (2,4,-l -phosphaallene reacted with dichlorocarbene to give 2-dichloromethylene-l-(2,4,6-tri-t-butylphenyl)-l -phosphirane. The structure was confirmed by X-ray crystal structure analysis. A similar isomerization product was obtained in the reaction of dichlorocarbene with 3-phenyl-l-(2,4,6-trit-butylpheny1)-1 -phosphaallene.

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