α-Addition of Dichlorocarbene to Cyclohexyl Isonitrile
✍ Scribed by Dr. A. Halleux
- Publisher
- John Wiley and Sons
- Year
- 1964
- Tongue
- English
- Weight
- 120 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
## Abstract A new product arising from the reaction of dichlorocarbene with norbornadiene, 6__endo__‐(2,2‐dichlorovinyl)‐__cis__‐bicyclo[3.1.0]hex‐2‐ene, is described. It does not arise from the normal __exo__‐l,2‐adduct, but possibly originates by sigmatropic rearrangement of an initially formed z
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
a-Carbonylcarbenes (2a-c) generated by UV photolysis of 2-diazophenylacetic acid (1a), its methyl ester (1b) and 4-diazo-3-isochromanone (1c) in aqueous solution undergo conjugate addition of water across the entire carbonylcarbene moiety to give enols (3a-c) of the corresponding a-hydroxycarbonyl c