Two new organo-templated three-dimensional 6uorinated titanium phosphates Ti 4 (HPO 4 ) 2 (PO 4 ) 4 F 2 ' C 4 N 2 H 12 ' H 2 O 1 and Ti 4 (HPO 4 ) 2 (PO 4 ) 4 F 2 ' C 2 N 2 H 10 ' H 2 O 2 have been prepared hydrothermally in the presence of piperazine (C 4 N 2 H 10 ) and ethylenediamine (C 2 N 2 H 8
The 2-methyl 4-nitroanilinium dihydrogenmonophosphate, C7H9N2O+2 · H2PO−4, a layer structure which evidences the structural properties of (H2PO−4)n flexible polyanion
✍ Scribed by R. Masse; J.P. Levy
- Book ID
- 103247447
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 515 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0022-4596
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📜 SIMILAR VOLUMES
A chain-like zincophosphate [Zns(HPO4)8(H2PO4)8]\*[(C2HsN)s] -4H20 was obtained at room temperature from a ZnO/PzOs/dimethylamine/H20 mixture. The crystal structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic a=l,26450(7)nm, b=l.08477(5)nm, c=1.46311(4)nm, 13=98.79
2.5 , monoclinic C2/m, a ؍ 18.425(4) A ˚, c ؍ 8.954(2) A ˚,  ؍ 93.69(2) 0 , V ؍ 1221.1(4) A ˚3, Z ؍ 4, D calc ؍ 2.423 g cm ؊3 ; 2 ؒ H 2 O, H 4 F 2 K 2 O 13 P 2 V 3 , triclinic P1, a ؍ 7.298(1) A ˚, b ؍ 8.929(2) A ˚, c ؍ 10.090(2) A ˚, ␣ ؍ 104.50(2) 0 ,  ؍ 100.39(2) 0 , ␦ ؍
A new layered tin(II) phosphate [Sn 2 (PO 4 ) 2 ] 2؊ [C 2 N 2 H 10 ] 2؉ • H 2 O was synthesized by hydrothermal technique. It crystallizes in monoclinic space group P2 1 /c (No. 14) with lattice parameters a ؍ 9.4112(1) A s ; b ؍ 8.5998(1) A s ; c ؍ 15.9921(2) A s ; ؍ 100.009(1)°; V ؍ 12
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