𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The (1) 3Σg+ electronic state of Cs2

✍ Scribed by C. Amiot; J. Verges


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
566 KB
Volume
116
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


Laser-induced fluokcence of Csz molecuks. recorded by high-rescktian Fourier spectroscopy, has been used for the fist spectroscopic identification of the lowest gerade triplet (1) '2: electronic state. This state can be described by tbe molecular parameters: -T, = 11602.10 cm-?, B, = 8.23 X 10m3 cm-', D,= 2.56 X 10m9 cm-' and R, -55425 44. Detern,ination of the absolute vibrational numbering will require further experiments.


📜 SIMILAR VOLUMES


The first two excited 1Σg+ states of Cs2
✍ C. Amiot; C. Crepin; J. Verges 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 240 KB

Laser-induced fluoresccncc of Cs2 molecules in the infrared region (4000-9000 cm-') has been observed using scvcral cnciting wavelengths from an argon-ion laser and from a ring dye laser. Accuntc molecular constants for the fit two cscited tZi electronic states arc derived from spectra rccordcd at h

All electron GVB/CI potential curves for
✍ Stephen P. Walch; Charles W. Bauschlicher Jr.; Per E.M. Siegbahn; Harry Partridg 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 383 KB

Alklcctron CVB/Cl potenrlsl curves haw been obtamcd for the X 1 r; SIPIC ol Cs2 usmg L large gsussix~ basis set. Cor- rclatlon oi the 5s. 5p ulcc~rons 1s found to Icad ro a sgntiicannt bond shonenmg eiicct. The calculxcd R, and Dc arc III WIsonablc agrccmcnt wh c~pciimcnt of the R, IS conccted ior t

The KRb (2)3Σ+ Electronic State
✍ C. Amiot 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 151 KB

High-resolution spectra of the (3) 1 ⌸ 3 (2) 3 ⌺ ϩ system of the KRb molecule, obtained after excitation with fixed frequencies Ar ϩ laser lines, were recorded on a Connes-type Fourier transform interferometer. Molecular constants of the first 14 vibrational levels of the (2) 3 ⌺ ϩ state are determi

Collision-induced fluorescence of Cs2: t
✍ R. Polly; D. Gruber; L. Windholz; H. Jäger 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 573 KB

We report the observation of a band system between 510 and 540 nm in laser induced fluorescence spectra of Cs2 excited by the Ar + laser lines Aexc = 488 nm, Aexc = 496.5 nm and A~xc = 501.7 nm. Using potential energy curves of Cs2 and performing quantum mechanical simulations of the spectra we assi

Resonance Raman scattering in the 1Σg+ →
✍ R.A. Desiderio; D.P. Gerrity; B.S. Hudson 📂 Article 📅 1985 🏛 Elsevier Science 🌐 English ⚖ 399 KB

Resonance Raman spectra of C& are presented at excltatlon wavelengths of 204 and 200 nm. Both spectra show achvlty III the symmetnc (~1) stretch and bendmg (~2) modes consistent with a bent, symmetnuLly stretched \* Bz('2:) upper state. In ad&tlon, these spectra show activity of the transition mvolv