Laser-induced fluokcence of Csz molecuks. recorded by high-rescktian Fourier spectroscopy, has been used for the fist spectroscopic identification of the lowest gerade triplet (1) '2: electronic state. This state can be described by tbe molecular parameters: -T, = 11602.10 cm-?, B, = 8.23 X 10m3 cm-
The first two excited 1Σg+ states of Cs2
✍ Scribed by C. Amiot; C. Crepin; J. Verges
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 240 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Laser-induced fluoresccncc of Cs2 molecules in the infrared region (4000-9000 cm-') has been observed using scvcral cnciting wavelengths from an argon-ion laser and from a ring dye laser. Accuntc molecular constants for the fit two cscited tZi electronic states arc derived from spectra rccordcd at high resolution by Fourier transform spccrroscopy. hlain molecular constants are: (2)'2;: Tc = 12114.090 cm-*, we= 23.350 cm-'. 8, = 7.45 X 10m3 cm-'. R, = 5.8316 A;
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