We report the observation of a band system between 510 and 540 nm in laser induced fluorescence spectra of Cs2 excited by the Ar + laser lines Aexc = 488 nm, Aexc = 496.5 nm and A~xc = 501.7 nm. Using potential energy curves of Cs2 and performing quantum mechanical simulations of the spectra we assi
Resonance Raman scattering in the 1Σg+ → 1B2 (1Σu+) transition of CS2
✍ Scribed by R.A. Desiderio; D.P. Gerrity; B.S. Hudson
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 399 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Resonance Raman spectra of C& are presented at excltatlon wavelengths of 204 and 200 nm. Both spectra show achvlty III the symmetnc (~1) stretch and bendmg (~2) modes consistent with a bent, symmetnuLly stretched * Bz('2:) upper state. In ad&tlon, these spectra show activity of the transition mvolvmg two quanta in the asymmetric (vg) stretch as well as progresslons m vt and 02 based upon thus asymmetric mode overtone.
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