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Tetrakis{μ-1-[2-(2-oxidoethyl­amino)­ethyl­imino­methyl]-2-naphtholato}tetrazinc(II)

✍ Scribed by You, Zhong-Lu ;Ma, Ji-Long ;Zhu, Hai-Liang ;Liu, Wei-Sheng

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
437 KB
Volume
60
Category
Article
ISSN
1600-5368

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{1-[2-(Dimethyl­amino)ethyl­imino­meth­y
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The title compound, [Ni(C 15 H 17 N 2 O)(NCS)], is a mononuclear Schiff base nickel(II) complex. The Ni II atom is coordinated by one O and two N atoms of the Schiff base ligand, and by one N atom of the thiocyanate ligand, forming a square-planar coordination.

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In the title mononuclear nickel(II) complex, [Ni(C 18 H 21- N 2 O)(NCS)], the Ni II atom is four-coordinated by the phenolate O, imine N and amine N atoms of the Schiff base ligand, and by the terminal N atom of a thiocyanate anion in a square-planar geometry. ## Related literature For the coordi

Bis{μ2-2-[2-(dimethyl­amino)ethyl­imino­
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The title complex, [Zn~2~(C~11~H~15~N~2~O)~2~Cl~2~] or [__L__ZnCl]~2~, where __L__ is the 2-[2-(dimethylamino)ethyliminomethyl]phenolate anion, is obtained by the reaction of __L__ZnEt with CDCl~3~ or by the reaction of __L__H with ZnCl~2~ in refluxing tetrahydrofuran. The Zn atoms in the dimeric co