Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.012 A Ê R factor = 0.044 wR factor = 0.102 Data-to-parameter ratio = 8.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Tetraethylammonium dichloro[N,N′-(4,5-dichloro-1,2-phenylene)bis(pyridine-2-carboxamidato)]chromate(III)
✍ Scribed by Choi, Yun Wee ;Kim, Shin Han ;Lee, Do Nam ;Kim, Cheal ;Kim, Youngmee
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 217 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Tetraethylammonium dichloro[N,N 0 0 0 -(4,5-dichloro-1,2-phenylene)bis(pyridine-2-carboxamidato)]chromate(III)
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The title coordination compound, (C 8 H 20 N)[Co(C 30 H 16 -N 4 O 4 S 4 ) 2 ]Cl, was formed on aerobic oxidation of a reaction mixture containing the doubly deprotonated N-(benzo[d]thiazol-2-ylmethyl)-2-mercaptobenzamide ligand and CoCl 2 in a 2:1 ratio. Aerobic conditions were employed to oxidize t
In the title compound, (C 8 H 20 N) [Fe(C 26 the Fe III ion is six-coordinate, forming a distorted octahedron with two pyridine and two deprotonated amide N atoms in the equatorial plane, while the metal-organic compounds m1790 # 2007 International Union of Crystallography
In the Mn^III^ complex of the title compound, [Mn^III^(C~18~H~12~N~4~O~2~)(H~2~O)~2~]ClO~4~, the Mn^III^ atom is coordinated by four N atoms from the bpb^2−^ [1,2-bis(pyridine-2-carboxamido)benzene] ligand located in the equatorial plane and two O atoms of water molecules at axial positions, yieldin