The title compound, C 20 H 14 F 4 N 4 O 2 , is centrosymmetric. The dihedral angle between the pyridine and benzene ring is 64.8 (4) . The crystal structure is stabilized by intermolecular N-HÁ Á ÁO hydrogen bonding.
N,N′-[(2,3,5,6-Tetrafluoro-1,4-phenylene)dimethylene]bis(pyridine-4-carboxamide)
✍ Scribed by He, Ming-Yang ;Chen, Sheng-Chun ;Chen, Qun
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 365 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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The title compound, C 20 H 14 F 4 N 4 O 2 , has been synthesized as part of our ongoing investigations into three-dimensional supramolecules or polymers with intriguing structural topologies and properties. The molecule crystallizes around a inversion centre, with one half-molecule in the asymmetric
Tetraethylammonium dichloro[N,N 0 0 0 -(4,5-dichloro-1,2-phenylene)bis(pyridine-2-carboxamidato)]chromate(III)
Single-crystal X-ray study T = 133 K Mean '(C±C) = 0.005 A Ê R factor = 0.049 wR factor = 0.140 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, C 18 H 21 NO 4 , the molecules form dimers by means of a pair of NÐHÁ Á ÁO hydrogen bonds. The 2(1H)pyridone ring displays a screw±boat conformation.