In the Mn^III^ complex of the title compound, [Mn^III^(C~18~H~12~N~4~O~2~)(H~2~O)~2~]ClO~4~, the Mn^III^ atom is coordinated by four N atoms from the bpb^2−^ [1,2-bis(pyridine-2-carboxamido)benzene] ligand located in the equatorial plane and two O atoms of water molecules at axial positions, yieldin
Aquachlorido[4,4′-dimethyl-N,N′-(o-phenylene)bis(pyridine-2-carboxamidato)]manganese(III) dimethylformamide solvate
✍ Scribed by Yang, Li ;Jiang, Zhaoqiong ;Zhou, Xiang-Ge
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 468 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, C 23 H 17 N 5 O 2 S 2 ÁC 3 H 7 NO, hydrogen bonds involving the amide groups and the pyridine N atoms force the two carboxamide groups and the central pyridine ring into the same plane. The solvent molecule is stabilized in the cavity formed by the two arms of the molecule by
In the title compound, (C 8 H 20 N) [Fe(C 26 the Fe III ion is six-coordinate, forming a distorted octahedron with two pyridine and two deprotonated amide N atoms in the equatorial plane, while the metal-organic compounds m1790 # 2007 International Union of Crystallography
Tetraethylammonium dichloro[N,N 0 0 0 -(4,5-dichloro-1,2-phenylene)bis(pyridine-2-carboxamidato)]chromate(III)
The title compound, [Cr(CN)~2~(C~12~H~8~N~2~)~2~][Cr(N~3~)~2~(C~18~H~12~N~4~O~2~)]·H~2~O, contains [Cr^III^(CN)~2~(phen)~2~]^+^ cations (phen is 1,10-phenanthroline) and [Cr^III^(N~3~)~2~(bpb)]^−^ anions [bpb is 1,2-bis(pyridine-2-carboxamido)benzene or __N__,__N__′-(__o__-phenylene)bis(pyridine-2-c