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Bis(tetra­ethyl­ammonium) bis­[N-(2-mercaptobenzo­yl)-1,3-benzothia­zole-2-carboxamidato]cobaltate(III) chloride

✍ Scribed by Frome, Michelle J. ;Cooper, Lisa E. ;Lewis, Breia J. ;Ferguson, Michael J. ;Daley, Christopher J. A.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
198 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title coordination compound, (C 8 H 20 N)[Co(C 30 H 16 -N 4 O 4 S 4 ) 2 ]Cl, was formed on aerobic oxidation of a reaction mixture containing the doubly deprotonated N-(benzo[d]thiazol-2-ylmethyl)-2-mercaptobenzamide ligand and CoCl 2 in a 2:1 ratio. Aerobic conditions were employed to oxidize the complex to the desired cobalt(III) oxidation state, but this also resulted in the oxidation of the coordinated ligand to an N-(2mercaptobenzoyl)-1,3-benzothiazole-2-carboxamide group.

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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.006 A Ê R factor = 0.041 wR factor = 0.113 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.