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Bis[N-(8-quinolyl)pyridine-2-carboxamidato]iron(III) perchlorate monohydrate

✍ Scribed by Li, Zhongfang ;Wang, Suwen ;Zhang, Qian ;Yu, Xianjin

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
504 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The asymmetric unit of the title compound, [Fe(C~15~H~10~N~3~O)~2~]ClO~4~·H~2~O, contains one iron(III) cation chelated by two N-(8-naphthyl)-2-pyridine-2-carboxamidate ligands via six N atoms, exhibiting an octahedral coordination geometry, a perchlorate anion and a water molecule. The Fe—N bond lengths are in the range 1.880 (3)–1.972 (3) Å. Each ligand is planar (r.m.s. deviations = 0.0314 and 0.0282 Å). The dihedral angle between the two ligand planes is 86.55 (1)°. There is a weak intermolecular hydrogen bond between the water and the perchlorate groups.

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Diaqua[N,N′-(o-phenylene)bis(pyridine-2-carboxamidato)-κ4N]manganese(III) perchlorate
✍ Zhang, Li-Fang 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 568 KB

In the Mn^III^ complex of the title compound, [Mn^III^(C~18~H~12~N~4~O~2~)(H~2~O)~2~]ClO~4~, the Mn^III^ atom is coordinated by four N atoms from the bpb^2−^ [1,2-bis(pyridine-2-carboxamido)benzene] ligand located in the equatorial plane and two O atoms of water molecules at axial positions, yieldin