Bis(N-(2-(2-hydroxyethylamino)ethyl)salicylideneimine)cobalt(III) chloride
✍ Scribed by Zhu, Hai-Liang ;Lin, Yong-Shan ;Meng, Fan-Jin ;Zou, Ying ;Wang, Da-Qi
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 493 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.006 A Ê R factor = 0.041 wR factor = 0.113 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
In the title complex, [Cr(C 11 H 15 N 2 O 2 ) 2 ]Cl, the Cr III ion is coordinated by four N atoms and two O atoms from two tridentate N-[2-(2-hydroxyethylamino)ethyl]salicylideneimine (sadol) ligands to form a distorted octahedron. A centrosymmetric dimer is constructed through the formation of O-H
In the title mononuclear cobalt(III) complex, [Co(C 11 H 14 -N 3 O 3 ) 2 ]NO 3 , the octahedral Co III atom is coordinated by two phenolate O atoms, two imine N atoms, and two amine N atoms from two Schiff base ligands. The Co III complex and the nitrate anion possess crystallographic twofold rotati
In the centrosymmetric title compound, [Zn(C 15 H 13 N 2 O 2 ) 2 -(C 5 H 5 N) 2 ], the Zn atom is chelated by the O and N atoms of two bidentate ligands. The coordination geometry of the central Zn atom is octahedral. The crystal packing is stabilized by intermolecular CÐHÁ Á ÁO interactions.
The title coordination compound, (C 8 H 20 N)[Co(C 30 H 16 -N 4 O 4 S 4 ) 2 ]Cl, was formed on aerobic oxidation of a reaction mixture containing the doubly deprotonated N-(benzo[d]thiazol-2-ylmethyl)-2-mercaptobenzamide ligand and CoCl 2 in a 2:1 ratio. Aerobic conditions were employed to oxidize t