Tetraethylammonium catena-μ4-chloro-di-μ-chloro-diargentate(I) and tetraethylammonium catena-μ4-bromo-di-μ-bromo-diargentate(I)
✍ Scribed by Helgesson, G. ;Jagner, S.
- Book ID
- 114505780
- Publisher
- International Union of Crystallography
- Year
- 1988
- Tongue
- English
- Weight
- 524 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0108-2701
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
In the title compound, [Cu 4 Br 4 (C 17 H 14 NP) 4 ]Á6CH 2 Cl 2 , the centrosymmetric Cu 4 Br 2 group is in a slightly distorted plane, forming a shuttle-like structure. Each of the Cu I ions is coordinated by two Br, N and P atoms, with metal±metal bonds between neighbouring Cu atoms.
Two compounds, [Cu5I5](SNC5H4)2 [i] and [Cu3I3](SNC5H4)2 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group I41/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper ato