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Dual graphs realized in the compounds di-μ3-4-mercaptopyridine catena-di-μ2-iodo-di-μ3-iodo-μ4-iodo penta copper(I) and di-μ3-4-mercaptopyridine-di-catena-iodo-di-μ3-iodo tri copper(I)

✍ Scribed by Ehsan Jalilian; Sven Lidin

Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 847 KB
Volume: 183
Category: Article
ISSN: 0022-4596
DOI: 10.1016/j.jssc.2010.09.009

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✦ Synopsis

Two compounds, Cu5I52 [i] and Cu3I32 [ii], were synthesized under hydrothermal conditions and the crystal structures were solved. Both compounds crystallized in space group I41/a. The iodide and the sulphur from mercaptopyridine are connected to copper atom, giving the copper atoms tetrahedral coordination geometry. The pyridine end of the organic moiety is nonbonding and fills the empty space around the tetrahedra formed from copper, sulphur and iodide.

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