catena-Poly{copper(I)-di-μ-bromo-copper(I)-2,3:2,4-[bis-μ-(1,4-oxathiane-S:S)]-[di-μ-bromo-dicopper(I)]-3,1:4,1-[bis-μ-(1,4-oxathiane-S:S)]}
✍ Scribed by Barnes, J. C. ;Paton, J. D.
- Book ID
- 114528946
- Publisher
- International Union of Crystallography
- Year
- 1982
- Weight
- 331 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0567-7408
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📜 SIMILAR VOLUMES
The title complex, [Hg~2~Br~4~(C~7~H~16~S~2~)]~n~, has a chain structure. Two bridging Br atoms and two terminal Br atoms coordinate to two Hg^II^ atoms, forming an (HgBr~2~)~2~ dimer, which is located on an inversion center. The 1,3-bis(ethylsulfanyl)propane ligands, which lie on a twofold axis, br
The crystal structure of the title compound, {[Cu(C 12 H 12 N 6 )]-ClO 4 } n , consists of a one-dimensional cationic copper(I) chain and uncoordinated ClO 4 À anions. In the cationic chain, the Cu I center, which lies on a crystallographic twofold rotation axis, is coordinated by two N atoms from t