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Di-μ3-bromo-di­bromo­tetrakis­[μ-di­phenyl(2-pyridyl)­phosphine)]­tetracopper(I) di­chloro­methane hexasolvate

✍ Scribed by Zhou, Jian-Liang ;Li, Yi-Zhi ;Zheng, He-Gen ;Xin, Xin-Quan ;Xu, Lin-Lin

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
402 KB
Volume
59
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cu 4 Br 4 (C 17 H 14 NP) 4 ]Á6CH 2 Cl 2 , the centrosymmetric Cu 4 Br 2 group is in a slightly distorted plane, forming a shuttle-like structure. Each of the Cu I ions is coordinated by two Br, N and P atoms, with metal±metal bonds between neighbouring Cu atoms.

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