Tetrachlorobis(dimethylamine)tin(IV)
✍ Scribed by Zhang, Yong ;Tong, Hong-Bo ;Liu, Dian-Sheng ;Huang, Su-Ping ;Zhou, Mei-Su
- Book ID
- 104484878
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 91 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [SnCl 4 (C 3 H 7 N) 2 ], the coordination geometry around the Sn atom is octahedral, with the two N atoms of dimethylamine in the axial sites. The Sn atom is at the center of the square formed by four Cl atoms. The title molecule lies on a crystallographic center of symmetry. The crystal structure has a moderate N-HÁ Á ÁCl hydrogen bond.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 203 K Mean '(C±C) = 0.005 A Ê R factor = 0.018 wR factor = 0.045 Data-to-parameter ratio = 24.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The molecule of the title compound, [Sn(C~4~H~9~)~2~(C~9~H~10~NO~2~)~2~], has twofold rotation symmetry. The geometry of the Sn atom is distorted tetrahedral. The dimethylamine substituent is twisted slightly from the benzene ring. The molecules are stabilized by weak intermolecular C—H...π interact
The tin(IV) atom in the title compound, [SnCl 4 (C 12 H 8 N 2 )], is six-coordinate in an octahedral geometry.