In the title compound, [SnCl 4 (C 3 H 7 N) 2 ], the coordination geometry around the Sn atom is octahedral, with the two N atoms of dimethylamine in the axial sites. The Sn atom is at the center of the square formed by four Cl atoms. The title molecule lies on a crystallographic center of symmetry.
trans-Tetrabromobis(dimethylamine)tin
✍ Scribed by Ritter III, Cole ;Groy, Thomas L. ;Kouvetakis, John
- Book ID
- 104479835
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 168 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Some non-H atoms missing Disorder in solvent or counterion R factor = 0.042 wR factor = 0.115 Data-to-parameter ratio = 19.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/
In the title compound, [CuBr 2 (C 12 H 8 N 2 ) 2 ], the Cu II ion lies on an inversion centre and exhibits a square planar coordination, with the two bromide ions and two N atoms of phenazine ligands in a trans con®guration. The CuÐBr and CuÐN distances are 2.382 (1) and 2.020 (2) A Ê , respectively
The single-crystal structure of the title compound, [NiBr 2 (C 13 H 13 P) 2 ], was determined by X-ray diffraction at 100 K. The molecule has approximately tetrahedral geometry and exhibits twofold symmetry in the solid state.