The Cd atom (site symmetry 2) in the title compound, adopts a trigonalbipyramidal coordination geometry but it tends towards a distorted pentagonal bipyramid owing to two long [2.674 (2) A ˚] CdÁ Á ÁO COO interactions from the asymmetrically coordinated acetate anions. The neutral metal complex, un
Tetraaquadithiocyanatonickel(II) tetrakis(2-amino-4,6-dimethylpyrimidine) dihydrate
✍ Scribed by Hemamalini, Madhukar ;Muthiah, Packianathan Thomas ;Butcher, Ray J.
- Book ID
- 104483238
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 433 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.045 wR factor = 0.115 Data-to-parameter ratio = 20.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
In the title polymer, {[Cu(C 8 H 4 O 4 )(C 6 H 9 N 3 )(H 2 O)]ÁC 6 H 9 N 3 } n , the Cu II ion approximates a distorted square-pyramidal geometry defined by an NO 4 donor set. Adjacent Cu II ions are bridged by isophthalate dianions to form a one-dimensional chain. Chains interact throughstacking in
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.033 wR factor = 0.086 Data-to-parameter ratio = 20.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.