Tetraaquabis(4,6-dioxidopyrimidin-1-ium-κN3)nickel(II)
✍ Scribed by Wang, Yu-Ting ;Lou, Xin-Hua ;Wang, Jian-Ge ;Fan, Yao-Ting
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 263 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the centrosymmetric title compound, [Co(C 11 H 9 N 2 O 4 ) 2 -(H 2 O) 4 ]Á0.5H 2 O, the Co II complex has a distorted octahedral coordination geometry with two monodentate ligands and four water molecules. The crystal packing is stabilized by intermolecular O-HÁ Á ÁO and C-HÁ Á ÁO hydrogen bonds
The Mn atom in the title compound, [Mn(C~12~H~8~NO~2~)~2~(H~2~O)~4~], lies on a centre of inversion in an all-__trans__-N~2~O~4~Mn octahedron; as the 4-(4-pyridyl)benzoate ligands bind to Mn through the pyridyl N atom, the compound is formally a zwitterion. Hydrogen bonds link adjacent zwitterions i