𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Tetraaquabis[3-(4-carboxyphenoxy)propionato-κO]copper(II) dihydrate

✍ Scribed by Xiao, Ying-Hui ;Kong, Li-Li ;Gao, Shan

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
363 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The title compound, [Cu(C 10 H 9 O 5 ) 2 (H 2 O) 4 ]Á2H 2 O, is a neutral mononuclear complex. The Cu II ion, which lies on an inversion center, displays an octahedral coordination geometry defined by two carboxylate O atoms of two different 3-(4-carboxyphenoxy)propionate ligands and four water molecules. The crystal structure is stabilized through strong O-HÁ Á ÁO hydrogen bonds involving uncoordinated carboxylic acid groups, and coordinated and solvent water molecules, leading to a three-dimensional network. The OÁ Á ÁO separations range from 2.623 (3) to 2.909 (3) A ˚and O-HÁ Á ÁO angles range from 163 (4) to 179 (4) .

Related literature

The structure of 3-(4-carboxyphenoxy)propionic acid, 3-(p-CPOPH 2 ), has been reported previously (Gao & Ng, 2006). In our previous work, a Co II complex of 3-(p-CPOP) has been characterized by X-ray crystallography (Xiao et al., 2006).

📜 SIMILAR VOLUMES

catena-Poly[[[diaquabarium(II)]-bis[μ-2-
catena-Poly[[[diaquabarium(II)]-bis[μ-2-(4-carboxyphenoxy)propionato-κ3O,O′:O′] dihydrate]
✍ Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 604 KB

In the crystal structure of the polymeric title compound, {[Ba(C~10~H~9~O~5~)~2~(H~2~O)~2~]·2H~2~O}~__n__~, the Ba^II^ atom is __O__,__O__′-chelated by the carboxylate end of two 2-(4-carboxyphenoxy)propionate monoanions, and is coordinated by two water molecules. It also interacts with the carboxyl

Bis[3-(4-carboxyphenoxy)propionato-κO]bi
Bis[3-(4-carboxyphenoxy)propionato-κO]bis[3-(4-carboxyphenoxy)propionic acid-κO]bis(pyridine-κN)cobalt(II)
✍ Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 777 KB

The title complex, [Co(C 10 H 9 O 5 ) 2 (C 10 H 10 O 5 ) 2 (C 5 H 5 N) 2 ], is a neutral mononuclear complex. The Co II atom, which lies on a centre of symmetry, has a distorted octahedral geometry involving two O atoms of the 3-(4-carboxyphenoxy)propionate groups, two O atoms of the 3-(4-carboxyphe

catena-Poly[[[aquabis[3-(4-carboxyphenox
catena-Poly[[[aquabis[3-(4-carboxyphenoxy)propionato-κ2O,O′]zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] dihydrate]
✍ Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 785 KB

In the title compound, {[Zn(C~10~H~9~O~5~)~2~(C~10~H~8~N~2~)(H~2~O)]·2H~2~O}~__n__~, the Zn atom, which lies on a twofold rotation axis, has a distorted pentagonal–bipyramidal geometry, involving four O atoms from two 3-(4-carboxyphenoxy)propionate groups, two N atoms from two 4,4′-bipyridine ligand

Tetra­aqua­bis[4-(dimethyl­amino)benzoat
Tetra­aqua­bis[4-(dimethyl­amino)benzoato-κO]manganese(II) dihydrate
✍ Hökelek, Tuncer ;Necefoğlu, Hacali 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 177 KB

The title Mn^II^ complex, [Mn(C~9~H~10~NO~2~)~2~(H~2~O)~4~]·2H~2~O, is monomeric and centrosymmetric. It contains two 4-dimethylaminobenzoate ligands, four coordinated and two uncoordinated water molecules, all ligands being monodentate. The four O atoms in the equatorial plane around the Mn atom fo

catena-Poly[[aqua(N,N-dimethylformamide-
catena-Poly[[aqua(N,N-dimethylformamide-κO)strontium(II)]-bis[μ-2-(4-carboxyphenoxy)propionato-κ3O,O′:O′]]
✍ Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 609 KB

In the crystal structure of the polymeric title compound, [Sr(C~10~H~9~O~5~)~2~(C~3~H~7~NO)(H~2~O)]~__n__~, the Sr^II^ atom is __O__,__O__′-chelated by the carboxylate end of two 2-(4-carboxyphenoxy)propionate monoanions, and is coordinated by a water molecule and a dimethylformamide (DMF) molecule.