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catena-Poly[[[aquabis[3-(4-carboxyphenoxy)propionato-κ2O,O′]zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] dihydrate]

✍ Scribed by Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
785 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, {[Zn(C~10~H~9~O~5~)~2~(C~10~H~8~N~2~)(H~2~O)]·2H~2~O}~n~, the Zn atom, which lies on a twofold rotation axis, has a distorted pentagonal–bipyramidal geometry, involving four O atoms from two 3-(4-carboxyphenoxy)propionate groups, two N atoms from two 4,4′-bipyridine ligands and one water molecule, also lying on the symmetry axis. 4,4′-Bipyridine ligands link adjacent Zn atoms, forming a one-dimensional chain structure. Furthermore, a three-dimensional supramolecular network is buildt up via hydrogen bonding and π–π stacking interactions [centroid–centroid distance 3.9096 (9) Å].

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