𝔖 Bobbio Scriptorium
✦   LIBER   ✦

catena-Poly[[diaquabis[(4-nitrophenylsulfinyl)acetato-κO]zinc(II)]-μ-4,4′-bipyridine-κ2N:N′]

✍ Scribed by Hou, Yan-Jun ;Yu, Ying-Hui ;Sun, Zhi-Zhong ;Li, Bai-Yan ;Hou, Guang-Feng

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
696 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title coordination polymer, [Zn(C 8 H 6 NO 5 S) 2 -(C 10 H 8 N 2 )(H 2 O) 2 ] n , each Zn II ion is in a slightly distorted octahedral coordination environment, formed by two carboxylate O atoms from two (4-nitrophenylsulfinyl)acetate ligands, two N atoms from bipyridine ligands and two water molecules. The Zn II ions and the bipryidine ligands lie on crystallographic twofold axes with the Zn II ions linked by bipyridine ligands into a one-dimensional chain structure. In the crystal structure, intermolecular O-HÁ Á ÁO hydrogen bonds link one-dimensional chains into a three-dimensional network.

Related literature

For synthetic background, see: Ghosh et al. (2005), and for previously published structures related to the topic, see:

📜 SIMILAR VOLUMES

catena-Poly[[diaquabis[(4-chlorophenylsu
catena-Poly[[diaquabis[(4-chlorophenylsulfinyl)acetato-κO]zinc(II)]-μ-4,4′bipyridine-κ2N:N′]
✍ Hou, Yan-Jun ;Li, Bai-Yan ;Yu, Ying-Hui ;Sun, Zhi-Zhong ;Hou, Guang-Feng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 829 KB

In the title coordination polymer, [Zn(C 8 H 6 ClO 3 S) 2 -(C 10 H 8 N 2 )(H 2 O) 2 ] n , the Zn II atom exists in an octahedral coordination environment that is formed by two carboxylate O atoms from two (4-chlorophenylsulfinyl)acetate ligands, two N atoms from two bipyridine ligands and two water

catena-Poly[[diaquabis[(4-chlorophenylsu
catena-Poly[[diaquabis[(4-chlorophenylsulfinyl)acetato-κO]cobalt(II)]-μ-4,4′-bipyridine-κ2N:N′]
✍ Hou, Yan-Jun ;Yu, Ying-Hui ;Sun, Zhi-Zhong ;Li, Bai-Yan ;Hou, Guang-Feng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 828 KB

In the title coordination polymer, [Co(C 8 H 6 ClO 3 S) 2 -(C 10 H 8 N 2 )(H 2 O) 2 ] n , the Co II atom exists in an octahedral coordination environment formed by two carboxylate O atoms from two (4-chlorophenylsulfinyl)acetate ligands, two N atoms from bipyridine ligands and two water molecules. T

catena-Poly[[[aquabis[3-(4-carboxyphenox
catena-Poly[[[aquabis[3-(4-carboxyphenoxy)propionato-κ2O,O′]zinc(II)]-μ-4,4′-bipyridine-κ2N:N′] dihydrate]
✍ Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 785 KB

In the title compound, {[Zn(C~10~H~9~O~5~)~2~(C~10~H~8~N~2~)(H~2~O)]·2H~2~O}~__n__~, the Zn atom, which lies on a twofold rotation axis, has a distorted pentagonal–bipyramidal geometry, involving four O atoms from two 3-(4-carboxyphenoxy)propionate groups, two N atoms from two 4,4′-bipyridine ligand