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catena-Poly[[diaquabis[(4-chlorophenylsulfinyl)acetato-κO]cobalt(II)]-μ-4,4′-bipyridine-κ2N:N′]

✍ Scribed by Hou, Yan-Jun ;Yu, Ying-Hui ;Sun, Zhi-Zhong ;Li, Bai-Yan ;Hou, Guang-Feng

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 828 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680702065x

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✦ Synopsis

In the title coordination polymer, [Co(C 8 H 6 ClO 3 S) 2 -(C 10 H 8 N 2 )(H 2 O) 2 ] n , the Co II atom exists in an octahedral coordination environment formed by two carboxylate O atoms from two (4-chlorophenylsulfinyl)acetate ligands, two N atoms from bipyridine ligands and two water molecules. The Co II atom lies on a twofold rotation axis. Bridging by the bipyridine ligand leads to a linear chain structure, and intermolecular O-HÁ Á ÁO hydrogen bonds link the chains into a three-dimensional network. Related literature For related literature, see: Ghosh et al. (2005); Nobles & Thompson (1965).

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