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catena-Poly[[[diaquabarium(II)]-bis[μ-2-(4-carboxyphenoxy)propionato-κ3O,O′:O′] dihydrate]

✍ Scribed by Kong, Li-Li ;Gao, Shan ;Huo, Li-Hua ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
604 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the crystal structure of the polymeric title compound, {[Ba(C~10~H~9~O~5~)~2~(H~2~O)~2~]·2H~2~O}~n~, the Ba^II^ atom is O,O′-chelated by the carboxylate end of two 2-(4-carboxyphenoxy)propionate monoanions, and is coordinated by two water molecules. It also interacts with the carboxylate O atom of two adjacent monoanions; these bonds give rise to a chain structure along the c axis. Meanwhile, the carboxyl –CO~2~H end of the anion interacts with an acceptor site [O...O = 2.608 (2) Å]; this interaction and hydrogen bonding involving the coordinated and lattice water molecules give rise to a three-dimensional network. The eight coordinating O atoms comprise a square-antiprism around the metal atom, which lies on a special position of site symmetry 2.

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