“Tethered” Ru(II) Catalysts for Asymmetric Transfer Hydrogenation of Ketones
✍ Scribed by Cheung, Fung Kei (Kathy); Hayes, Aidan M.; Hannedouche, Jerome; Yim, Aveline S. Y.; Wills, Martin
- Book ID
- 126901602
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 200 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
Asymmetric hydrogenationofphenylthio ketonesusing chiralRu(II) catalystsis reported. Completeconversionsandenantiomericexcessesup to 98%wereobtained.
Asymmetric hydrogenation of prochiral keto groups with ~S,S) and (R,R)-SkewphosRuBr 2 prepared in situ is described. Good enantiomeric ex~ e.~.w.~ up t~, 95~ were obtained.
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