Skewphos-Ru(II): An efficient catalyst for asymmetric hydrogenation of functionalized ketones
✍ Scribed by Delphine Blanc; Jean-Christophe Henry; Virginie Ratovelomanana-Vidal; Jean-Pierre Genêt
- Book ID
- 104257857
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 212 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Asymmetric hydrogenation of prochiral keto groups with ~S,S) and (R,R)-SkewphosRuBr 2 prepared in situ is described. Good enantiomeric ex~ e.~.w.~ up t~, 95~ were obtained.
📜 SIMILAR VOLUMES
Asymmetric hydrogenationofphenylthio ketonesusing chiralRu(II) catalystsis reported. Completeconversionsandenantiomericexcessesup to 98%wereobtained.
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