1998 organo-phosphorus compounds, isocyclic C derivatives organo-phosphorus compounds, isocyclic C derivatives S 0084 ## 32 -228 Asymmetric Hydrogenation of Vinylphosphonic Acids and Esters with Chiral Ru(II) Catalysts. -The first asymmetric catalytic hydrogenation of vinylphosphonic acids (I) is
ChemInform Abstract: Asymmetric Hydrogenation of Phenylthio Ketones with Chiral Ru(II) Catalysts.
β Scribed by J.-P. TRANCHIER; V. RATOVELOMANANA-VIDAL; J.-P. GENET; S. TONG; T. COHEN
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Asymmetric Hydrogenation of Ξ²-Ketophosphonates and Ξ²-Ketothiophosphonates with Chiral Ru(II) Catalysts. -Ξ²-Hydroxyphosphonates (II) and Ξ²-hydroxythiophosphonates such as (IV) are synthesized by hydrogenation of the corresponding . beta.-keto compounds (I) and (III). The use of a chiral Ru(II) catal