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ChemInform Abstract: Asymmetric Hydrogenation of Vinylphosphonic Acids and Esters with Chiral Ru(II) Catalysts.

✍ Scribed by J.-C. HENRY; D. LAVERGNE; V. RATOVELOMANANA-VIDAL; J.-P. GENET; I. P. BELETSKAYA; T. M. DOLGINA

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 organo-phosphorus compounds, isocyclic C derivatives organo-phosphorus compounds, isocyclic C derivatives S 0084

32 -228

Asymmetric Hydrogenation of Vinylphosphonic Acids and Esters with Chiral Ru(II) Catalysts.

-The first asymmetric catalytic hydrogenation of vinylphosphonic acids (I) is reported. In the presence of homogeneous in situ generated chiral Ru(II) catalysts the corresponding arylethylphosphonic acids (II) are obtained with up to 86% e.e. -(HENRY,

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