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The “Reverse-Tethered” Ruthenium(II) Catalyst for Asymmetric Transfer Hydrogenation: Further Applications.

✍ Scribed by David J. Morris; Aidan M. Hayes; Martin Wills

Publisher
John Wiley and Sons
Year
2007
Weight
46 KB
Volume
38
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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## Abstract The chiral amino amide **3** was derived from L‐proline and used for the [RuCl~2~(__p__‐cymene)]~2~‐catalyzed asymmetric transfer hydrogenation of prochiral ketones performed in water. Moderate to good chemical selectivities (up to 95% yield) and enantioselectivities (up to 90% ee) were