Temperature dependent 13C and 3sC1 NMR relaxation times in liquid CC1 are used to derive values of both the reorientational and angular momentum correlation times 70,~ and Tj. The relationship found between i-9,2 and TJ is k quantitntive qreement with the extended J-diffusion model for molecular reo
Tests of models of molecular reorientation in liquids
β Scribed by R.M. Lynden-Bell; I.R. McDonald
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 431 KB
- Volume
- 89
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Compurcr slmularrons oi tetrahedral molecules have been used to test some common models for molcculv reorients don III bqulds. At high densny, the Fohbcr-Planck and Iddfuslon models and a three-term hlon approwmarlon ate all unnrtsfactory: UIJ two latter provide reasonable lits at low density.
π SIMILAR VOLUMES
## Abstract The vibrational relaxation and molecular reorientational processes in liquids have been studied in some carbonylβcontaining molecules using the acetonitrile (ACN) solvent. The vibrational and reorientational processes have been studied in correspondence with correlation times. The scree