Compurcr slmularrons oi tetrahedral molecules have been used to test some common models for molcculv reorients don III bqulds. At high densny, the Fohbcr-Planck and Iddfuslon models and a three-term hlon approwmarlon ate all unnrtsfactory: UIJ two latter provide reasonable lits at low density.
Anisotropy of molecular reorientation in liquid methylene chloride.
β Scribed by A. Hacura
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 299 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0167-7322
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π SIMILAR VOLUMES
Molecular dynamics simulation and diffraction (X-ray and neutron) studies are compared on methylene chloride with aiming at the determination of the liquid structure. Beyond that, the capabilities of the methods to describe liquid structure are discussed. For the studied liquid, the diffraction meth
## Abstract Although dibromomethane is a simple molecule, little work has been directed toward the analysis of its reorienβtational motion. This is surprising, since two components of its inertia tensor are nearly degenerate and may, in principle, be treated as a quasiβsymmetric top. The ^13^C spin