## Abstract It is demonstrated that in a case where neither the proton nor the natural‐abundance ^13^C‐satellite spectra of a partially oriented molecule carry enough structural information, one can determine the entire molecular geometry by the combined use of several liquid crystals as solvents.
✦ LIBER ✦
13C and 35Cl NMR relaxation in liquid CCl4. A test of the extended J-diffusion model for molecular reorientation
✍ Scribed by Kenneth T. Gillen; Joseph H. Noggle; Thomas K. Leipert
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 468 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Temperature dependent 13C and 3sC1 NMR relaxation times in liquid CC1 are used to derive values of both the reorientational and angular momentum correlation times 70,~ and Tj. The relationship found between i-9,2 and TJ is k quantitntive qreement with the extended J-diffusion model for molecular reorientation.
📜 SIMILAR VOLUMES
The rα-structure of partially oriented 1
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G. Dombi; J. Amrein; P. Diehl
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Article
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1980
🏛
John Wiley and Sons
🌐
English
⚖ 322 KB