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Study of vibrational relaxation and molecular reorientation in liquids: a Raman spectroscopic study

✍ Scribed by Th. Gomti Devi

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
136 KB
Volume
41
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

The vibrational relaxation and molecular reorientational processes in liquids have been studied in some carbonyl‐containing molecules using the acetonitrile (ACN) solvent. The vibrational and reorientational processes have been studied in correspondence with correlation times. The screening effect due to dielectric has been studied and the Onsager reaction field model has been tested. The study shows that repulsive types of intermolecular forces play an important role in complex systems. Copyright Β© 2010 John Wiley & Sons, Ltd.

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