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Raman studies of reorientational relaxation of cyclohexane in the liquid state

✍ Scribed by T. Bien; G. Döge

Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
374 KB
Volume
12
Category
Article
ISSN
0377-0486

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✦ Synopsis

Abstract

Reorientational correlation functions have been obtained from the analysis of the totally symmetric vibrations ν~4~, ν~5~ and ν~2~ of liquid cyclohexane. For the interpretation of the data, the Kubo line shape theory was assumed to be valid. The most reliable results were obtained from the ν~4~ vibration and indicated that reorientational relaxation occurs close to the Debye limit of rotational diffusion. The data are compared with NMR results given in the literature. The effects of rotational‐vibrational coupling are discussed.

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