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Termination by primary radicals in vinyl polymerization

โœ Scribed by Bamford, C. H.; Jenkins, A. D.; Johnston, R.

Book ID
127058632
Publisher
Royal Society of Chemistry
Year
1959
Weight
678 KB
Volume
55
Category
Article
ISSN
0014-7672

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๐Ÿ“œ SIMILAR VOLUMES

Studies in vinyl chloride polymerization
Studies in vinyl chloride polymerization. Determination of primary radical termination by initiator fragment method
โœ Ebhodaghe F. Okieimen ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 195 KB

The rate of vinyl chloride polymerization initiated by doubly labelled benzoyl peroxide in dichloroethane at 60 ยฐ was measured dilatometrically. The extent of primary radical termination, evaluated from the assay of the polymer samples recovered at 10% conversion, is compared with values deduced fro

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Non-ideal kinetics in vinyl polymerization: Note on primary radical termination in benzoyl peroxide initiated polymerization of vinyl chloride in dichloroethane
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The kinetics of vinyl chloride polymerization initiated by benzoyl peroxide doubly labelled with t4C and 3H were studied in 1,2-dichloroethane solution at 60 ยฐ. The importance of primary radical termination in the polymerization is examined by kinetic analysis and by analysis of polymers for combine