The kinetics of vinyl chloride polymerization initiated by benzoyl peroxide doubly labelled with t4C and 3H were studied in 1,2-dichloroethane solution at 60 ยฐ. The importance of primary radical termination in the polymerization is examined by kinetic analysis and by analysis of polymers for combine
Studies in vinyl chloride polymerization. Determination of primary radical termination by initiator fragment method
โ Scribed by Ebhodaghe F. Okieimen
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 195 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0014-3057
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โฆ Synopsis
The rate of vinyl chloride polymerization initiated by doubly labelled benzoyl peroxide in dichloroethane at 60 ยฐ was measured dilatometrically. The extent of primary radical termination, evaluated from the assay of the polymer samples recovered at 10% conversion, is compared with values deduced from analysis of the kinetic data.
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