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Non-ideal kinetics in vinyl polymerization: Note on primary radical termination in benzoyl peroxide initiated polymerization of vinyl chloride in dichloroethane

✍ Scribed by Solution E.F. Okieimen

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
265 KB
Volume
17
Category
Article
ISSN
0014-3057

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✦ Synopsis

The kinetics of vinyl chloride polymerization initiated by benzoyl peroxide doubly labelled with t4C and 3H were studied in 1,2-dichloroethane solution at 60 °. The importance of primary radical termination in the polymerization is examined by kinetic analysis and by analysis of polymers for combined initiator fragments.

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