Non-ideality in vinyl polymerisation—IX. Note on secondary dissociation of primary radicals

Non-ideal kinetics in vinyl polymerizati

Non-ideal kinetics in vinyl polymerization: Note on primary radical termination in benzoyl peroxide initiated polymerization of vinyl chloride in dichloroethane

✍ Solution E.F. Okieimen 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 265 KB

The kinetics of vinyl chloride polymerization initiated by benzoyl peroxide doubly labelled with t4C and 3H were studied in 1,2-dichloroethane solution at 60 °. The importance of primary radical termination in the polymerization is examined by kinetic analysis and by analysis of polymers for combine