The kinetics of vinyl chloride polymerization initiated by benzoyl peroxide doubly labelled with t4C and 3H were studied in 1,2-dichloroethane solution at 60 °. The importance of primary radical termination in the polymerization is examined by kinetic analysis and by analysis of polymers for combine
✦ LIBER ✦
Non-ideal kinetics in vinyl polymerization primary radical termination and chain transfer to solvent in benzoyl peroxide initiated polymerization of vinyl acetate in benzene
✍ Scribed by Ebhodaghe F. Okieimen
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 244 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0032-3861
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📜 SIMILAR VOLUMES
Non-ideal kinetics in vinyl polymerizati
✍
Solution E.F. Okieimen
📂
Article
📅
1981
🏛
Elsevier Science
🌐
English
⚖ 265 KB
Non-ideality in vinyl polymerization—IV.
✍
Pramil C. Deb; Swati Ray
📂
Article
📅
1978
🏛
Elsevier Science
🌐
English
⚖ 257 KB
Vinyl acetate was polymerized in bulk and in benzene at 50°C using a wide range of concentrations of azobisisobutyronitrile. Values offk (the efficiency of initiator) and kr,,/klk p (the characteristic constant of primary radical termination) were found to be 0.53 and 2.00 x 104 respectively from da