Template-Assisted Solvothermal Synthesis of Five Copper(I)−Thioantimonate(III) Composites: Crystal Structures and Optical and Thermal Properties of (C 6 N 2 H 18 ) 0.5 Cu 2 SbS 3 , (C 4 N 3 H 15 ) 0.5 Cu 2 SbS 3 , (C 8 N 4 H 22 ) 0.5 Cu 2 SbS 3 , (C 4 N 3 H 14 )Cu 3 Sb 2 S 5 , and (C 6 N 4 H 20 ) 0.5 Cu 3 Sb 2 S 5
✍ Scribed by Spetzler, V.; Näther, C.; Bensch, W.
- Book ID
- 127133725
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 500 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0020-1669
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi
## Abstract As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.