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Temperature Dependent Rate Coefficient for the Reaction O( 3 P) + NO 2 → NO + O 2

✍ Scribed by Gierczak, Tomasz; Burkholder, James B.; Ravishankara, A. R.

Book ID
125989950
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
123 KB
Volume
103
Category
Article
ISSN
1089-5639

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The molecular modulation spectroscopic technique was employed to study the kinetics of NO3 radicals produced in the 253.7 nm photolysis of flowing gas mixtures of HNO3/CH4/O2 at room temperature. By computer fitting of the NO, temporal behavior, a rate coefficient of (2.3 ? 0.7) x lo-'' cm3 molecule