Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ϩ NO) ϭ (8 Ϯ 3 2 2 and were de-Ϫ12 Ϫ12 3 Ϫ1 Ϫ1 2) ϫ
ChemInform Abstract: A Temperature-Dependent Kinetics Study of the Important Stratospheric Reaction O(3P) + NO2 → O2 + NO.
✍ Scribed by E. G. Estupinan; J. M. Nicovich; P. H. Wine
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0931-7597
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The rate constants of the reactions of ethoxy (C 2 H 5 O), i-propoxy (i-C 3 H 7 O) and npropoxy (n-C 3 H 7 O) radicals with O 2 and NO have been measured as a function of temperature. Radicals have been generated by laser photolysis from the appropriate alkyl nitrite and have been detected by laser-