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Temperature-dependent N2(A3Σ+u) quenching rate coefficients

✍ Scribed by T.G. Slanger; B.J. Wood; G. Black


Publisher
Elsevier Science
Year
1973
Weight
244 KB
Volume
2
Category
Article
ISSN
0047-2670

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The lime decay of N,(AjI: ) produced by pulsed phololysls of GIN, a1 193 nm erhlblls I~O componenls a fasi decay correspondmg IO pseudo-firsl-order quenchmg by GIN, and a much slouer decal correspondmg IO a chain process In which N?(A'Z; ) IS regenerated The iale conslanl for N,(A'T; ) qurnchng by

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Time-resolved fluorescence hscr-induced spectroscopy was used to determine the quencbin~ rates of the vibrations1 Icvets u' = 0,l and 2 of NG(B \*f+ \_,,) bv I& and Ne. For bolt2 quenchers rate constants mz found to base a depcndenoz upon \_ the vibrational escitation of the Ievef. Tlie radiative Ii