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Temperature dependence of the spinS=1/2 fluctuation rate and the low-spin versus high-spin transition in native chloroperoxidase

✍ Scribed by C. E. Schulz; P. Osmulski; Y. -M. Xia; P. G. Debrunner


Book ID
112683688
Publisher
Springer
Year
1994
Tongue
English
Weight
424 KB
Volume
91
Category
Article
ISSN
0304-3843

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Based on measurements of differential scanning calorimetry, the first-order character of the spin-state transition in Fe(bt),(NCS), is established (bt = 2,2'-bi-2-thiazoline). The transition arises at T, ' =180.9 K and T,l =171.2 K, and is characterized by AH = 9.55 kO.7 kJ mol-' and AS = 54.5 \*4 J