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Temperature dependence of Debye-Waller factors at a cooperative high-spin (5T2) ⇌ low-spin (1A1) transition in dithiocyanatobis(2,2'-bipyridyl)iron(II)

✍ Scribed by E. König; G. Ritter


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
249 KB
Volume
43
Category
Article
ISSN
0375-9601

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Hyperfine interactions have been studied at a cooperative 'T2 = ' Al transition in the solid complex Fe(4,7-(CH&-pher&(NCS)z employing an external field Helt = 40 kG and temperatures between 4.2 and 163OK (phen = l,iO-phenanthroline). At cryogenic temperatures, the isolated 'Al ground state may be

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