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Debye-waller factors and magnetism down to 1.00 K for the high-spin(5T2)⇌low-spin(1A1) transition in bis[2-(2-pyridylamino)-4-(2-pyridyl)thiazolato]iron(II)

✍ Scribed by E. König; G. Ritter; W. Irler; H.A. Goodwin; B. Kanellakopulos

Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
512 KB
Volume
39
Category
Article
ISSN
0022-3697

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Debye-Waller factors and magnetism down
Debye-Waller factors and magnetism down to 1.00 K for the high-spin (5T2) ⇌ low-spin (1A1) transition in Bis[2-(2-pyridylamino) -4-(2-pyridyl)thiazolato]iron(II) : E. König, G. Ritter, W. Irler, H.A. Goodwin, Institut fur Physikalische Chemie and Physikalishes Institut, University of Erlangen-Nürnberg, D-8520 Erlangen, W. Germany; and B. Kanellakopulos, Heisse Chemie, Kernforschungszentrum Karlsruhe, D-7500 Karlsruhe, W. Germany
✍ E. König; G. Ritter; W. Irler; H.A. Goodwin; B. Kanellakopulos 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 114 KB
Thermally induced high-spin (5T2) ⇌ low-
Thermally induced high-spin (5T2) ⇌ low-spin (1A1) transitions in bis[2-(2-pyridylamino)—4-(2-pyridyl)thiazole]iron(II) complexes: a Mössbauer effect study
✍ E. König; G. Ritter; H.A. Goodwin 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 403 KB

Employmg snmplcs cnrichcd to >90% in 57Fc, hlbssbducr cffcct studlcs dcmonstratc that high-spin (%2) := low-spm ('A1) transitions arc responsible for the peculiar tempcraturc dcpendcncc of the mdgnctlsm in ccrtam [fc(paptH)z ] X2 l nH20 complcxcs where paptH = 2-(2-pyridyhho) -4-(2-pyrldyl)thiai!olc

The high-spin low-spin equilibrium of ir
The high-spin low-spin equilibrium of iron(II) in FeII(TRIM)2(PhCO2) (ClO4): Observation and interpretation of a gradual 5T2↔1A1 spin-state conversion
✍ G. Lemercier; A. Bousseksou; S. Seigneuric; F. Varret; J.-P. Tuchagues 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 469 KB

The Fe"(TRIM),(PhCO,) (ClO,) spin crossover complex (TRIM = 4'-(4-methylimidazole )-2'-(2"-methylimidazole) imidazole, PhCOr = C6H5C02) has been synthesized and investigated by Miissbauer spectroscopy and magnetic susceptibility measurements as a function of temperature. The spin conversion is gradu